New device captures carbon dioxide by pumping it across a battery
摘要
美国特拉华大学James Buchen团队开发出一种基于电池的电化学碳捕集技术。该装置利用电池阴极产生的氢氧化物与二氧化碳反应，生成碳酸盐或碳酸氢盐，穿过隔膜到达阳极后，因pH降低而逆转反应，重新释放出二氧化碳气体并收集。研究称，这一方法比以往尝试更可行，且有望比当前主流的可逆过滤设计能耗更低、成本更便宜。
Equipment to capture carbon dioxide from ambient air or smokestacks generally works through a sort of reversible filter. Air is passed through granules or a liquid that absorbs the CO2, then that CO2-loaded substance undergoes a process (usually heating) that causes it to let go of all that CO2. The resulting gas can be collected in a separated stream.
It’s also possible to do a similar sort of operation on a smaller scale—like inside a battery. A new study from a team led by James Buchen of the University of Delaware demonstrates an example of a battery-based electrochemical carbon-capture technique that they say is more viable than previous attempts. It has the potential to require less energy—and therefore be cheaper—than the reversible-filter designs that currently dominate.
Carbon chemistry
The basic idea behind a device of this type is that hydroxide produced at the battery cathode reacts with CO2, converting it to carbonate or bicarbonate that passes through the separator membrane to the anode. There, the lower pH causes the reaction to reverse, with carbonate turning back into CO2 gas. The role of the cathode is to produce hydroxide ions; the role of the anode is to consume them.
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